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1. INTRODUCTION
The ceramic industry can be divided into two main
categories: red ceramics and white ceramics.
Red ceramics are typically associated with
large-scale structural uses in civil construction
(bricks, tiles, etc.), and are produced by using
rewood as the predominating energy source in
Brazil (EPE, 2018). White ceramics, on the other
hand, generally consist of higher-quality products
(ooring, tiles, porcelain, etc.) that serve more
specic functions and require a higher energy
intensity in manufacturing (e.g., in the drying
process). In this case, natural gas predominates in
Brazil as the main fuel along such a manufacturing
chain. Among the emerging uses of H₂, processes
involving high-temperature heat (above 400
ºC) can benet from this resource as a form of
decarbonization, presenting as a competitive
alternative to electrication (IEA, 2024; ENGIE,
2022). In this way, the energetic use of hydrogen
can help preserve existing industrial assets
and avoid the need for developing disruptive
technologies.
Green H₂, derived from water electrolysis using
renewable energy (such as hydric, solar, and
wind), is an energy source capable of serving this
class of processes as a substitute for fossil fuels.
In particular, the Brazilian electricity grid could be
suitable for green hydrogen production, since
hydropower stands out with a share of almost
60% as one of the main primary energy sources
(EPE, 2024). As long as the hydric scenario in
the country is favorable, the grid can sustain a
low-carbon intensity with reliable provision, for
example, facilitating the certication of hydrogen
in strict schemes (CCEE, 2024). Overall, the
combination of renewable electricity resources
in Brazil can allow elevated operational factors,
enabling the economic feasibility of electrolysis
projects while guaranteeing the environmental
attribute of hydrogen.
Notably, international experiences in the ceramics
industry have adopted pilot plants to use green
hydrogen. For example, a ceramic company in
Villareal, Spain, has invested in the GREENH2KER
decarbonization project, which aims to replace
50% of natural gas with green H₂ (IBERDROLA,
2021). Another recent experience that endorses
the technical feasibility of using a hydrogen-
natural gas mixture in the ceramic industry is a
project developed in Castellarano, Italy. Success
was reported for tests with fuel blends containing
7% H2 to decarbonize the operation of a kiln, and
there is an expectation to use mixtures with up to
50% H2 (IRIS, 2024).
Finally, although carbon credits tend to be the main
coproduct in economic assessments involving low-
carbon H2, the O2 coproduced in electrolysis is
usually neglected. Actually, only specic industrial
sectors (steel industry, healthcare systems in
hospitals, submarine projects) use it at relevant
scales (IEA, 2023). Dedicated O₂ production
systems tend to be costly for use in enhanced
combustion processes, and therefore combustion
is conducted commonly with air as comburent.
It is noteworthy that some studies are giving
purpose to this byproduct. Novaes et al. (2024)
evaluated a Power-to-Liquid process sourced
with green H2 to produce wax and syncrude as
main products. The revenue associated with O2
presented a share of 13% among the outputs,
being also almost four times more representative
than the selling of carbon credits. Assunção et al.
(2025) modeled the use of an electrolysis system
in order to supply H2 for fuel cell vehicles (i.e.,
ambulances) while O2 was stored for attending
to the healthcare systems in a hospital. Avoiding
the cost of buying O2 allowed a reduction of the
levelized cost of Hydrogen (LCOH) from 4.96 to
2.60 USD/kg. Finally, León et al. (2024) studied
a bolder model for a cement factory in Spain, in
which synfuels are produced by combining CO2
from ue gases and hydrogen from electrolysis;
the coproduced O2 was appraised through an
oxy-combustion applied to a calcination process.
Thus, the possibility of designating a concrete use
for O2 can promote the economic feasibility of H2
derived from water electrolysis.